منابع مشابه
1. Aluminum anodization
The history of electrochemical oxidation of aluminum dates back to the beginning of the last century. Anodic treatment of aluminum were intensively investigated to obtain protective and decorative films on its surface [1]. More recently, applications of porous alumina with a huge surface area and a relatively narrow pore size distribution have been exploited [2]. For example, several attempts t...
متن کاملThe Anodization of Aluminum for Nanotechnology Applications
This article is an introduction to anodization of aluminum, which is a subject of electrochemistry. Anodization of aluminum under a controlled electrochemical condition yields ordered porous alumina with a close-packed hexagonal array of cylindrical nanochannels. The diameter, density, and aspect ratio of pores can be tightly controlled by varying the anodization condition, which makes the poro...
متن کاملFormation of nanoscale pore arrays during anodization of aluminum
– A theory of the spontaneous formation of spatially regular hexagonal arrays of nanopores in aluminum oxide film growing during aluminum anodization is presented. Linear stability analysis shows that, in certain ranges of the applied voltage and electrolyte pH, the oxide film is unstable with respect to perturbations with a well-defined wavelength. The instability is caused by a positive feedb...
متن کاملSelf-ordered anodic aluminum oxide formed by H2SO4 hard anodization.
The self-ordering of nanoporous anodic aluminum oxide (AAO) in the course of the hard anodization (HA) of aluminum in sulfuric acid (H2SO4) solutions at anodization voltages ranging from 27 to 80 V was investigated. Direct H2SO4-HA yielded AAOs with hexagonal pore arrays having interpore distances D(int) ranging from 72 to 145 nm. However, the AAOs were mechanically unstable and cracks formed a...
متن کاملAluminum Zintl anion moieties within sodium aluminum clusters.
Through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations, we have established that aluminum moieties within selected sodium-aluminum clusters are Zintl anions. Sodium-aluminum cluster anions, Na(m)Al(n)(-), were generated in a pulsed arc discharge source. After mass selection, their photoelectron spectra were measured by a magnetic bo...
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ژورنال
عنوان ژورنال: Denki Kagaku oyobi Kogyo Butsuri Kagaku
سال: 1973
ISSN: 0366-9297,2434-2556
DOI: 10.5796/kogyobutsurikagaku.41.764